You Only Move Twice, which first aired on November 3, 1996, is the most famous of all Bond/Simpsons spoofs. In the episode, which is in part a spoof of You Only Live Twice,
James Bont escapes from Scorpio's laser table
Cypress Creek when Homer accepts a job at the GLOBEX Corporation. However, what Homer doesn't know is that GLOBEX is actually a front for for Hank Scorpio's evil organization that is bent on world domination. A few days into his tenure at GLOBEX, Homer is at a vending machine while Scorpio has his nemesis, James Bont, strapped down to a deadly Goldfinger-esque laser table. Using a coin in his pocket, Bont splits the laser beam in four directions to free himself, fires a hidden gas cartridge from his suit jacket and begins to run away. However, after hearing Scorpio's yell, Homer takes a break from purchasing snacks to tackle Bont, at which point the guards just shoot him: something a real Bond villain would never actually do. A few scenes later, when Homer goes to find Scorpio to submit his resignation, he finds Hank in the middle of a massive army fight between his goons and the army. There is also a scene where a woman is in a bikini, and pins a man down to the grond and crushes and kills him between her thighs, much resembling Xenia Onatopp. The whole scene is taken straight out of the end of You Only Live Twice, though Bont does not play a part. The episode's credits got a music theme to Hank Scorpio, like Auric Goldfinger in "Goldfinger".
The Simpsons 138th Episode Spectacular was a clip show of "rare footage and deleted scenes" from previous episodes. Basically, this premise gave the writers a chance to make a bunch of things up just for this episode. Segments included a robotic Richard Simmons, an alternate ending to the Who Shot Mr. Burns episodes, and a deleted scene from the episode where Mr. Burns opens a casino in Springfield. In this deleted scene, is a blackjack dealer at a table where Bond and a mix of Blofeld and Largo are playing cards. Standing behind them are Simpsons versions of Oddjob and Jaws. As Homer deals, the following dialogue takes place:
Blofeld: 20. Your move, Mr. Bond.
Bond: I'll take a hit, dealer. [Homer gives him a card] Joker! You were supposed to take those out of the deck.
Homer: Oh, sorry. Here's another one.
Bond: What's this card? "Rules for Draw and Stud Poker"?
Blofeld: What a pity, Mr. Bond. [Odd Job and Jaws grab Bond and drag him out]
Bond: But...but it's Homer's fault! I didn't lose. I never lose! Well, at least tell me the details of your plot for world domination.
Blofeld: Ho ho ho, I'm not going to fall for that one again